Locking a labile atropisomer: The biindolyl (R,R)‐2 consists of diastereomeric atropisomers ((this word should not be hyphenated as in the current pdf‐file)), which interconvert on the
NMR timescale at +30 °C but not at −10 °C. (R,R)‐2 was dibrominated providing the biindolyls 1 (M)‐ or (P)‐selectively, depending on the achiral reagent.
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NMR analysis and calibration. Figure 2 is an example of an
NMR spectrum of α-
lactose monohydrate powder, containing an insert of the region of interest 6-7 ppm where the α and β
proton peaks occur, on a larger scale. The α and β protons are the most deshielded atoms in the
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