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benzene venne scoperto nel 1825 dallo scienziato britannico Michael Faraday, che lo isolò dal petrolio e lo chiamò bicarburo di idrogeno.. Nel 1834 fu ricavata la formula empirica del
benzene e in seguito la sua formula molecolare (), che destò stupore in quanto fu la prima molecola conosciuta avente un numero uguale di atomi di carbonio e di atomi di idrogeno.
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